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Materials scientists and engineers, condensed matter physicists, physical and electrochemists, and electrical engineers come together in this volume to share recent advances in four inter-related materials fields, namely: semiconductor nanocrystals; porous silicon; nanocrystalline, microcrystalline and polycrystalline films; single-crystal quantum structures, including dots, wires and wells. The unifying scientific theme common to these fields is the modification of the properties of semiconductors that results from electronic confinement. The common challenge in each of these fields is to understand, and often to minimize, the influence of structural features including surfaces, interfaces, grain boundaries, and intergranular phases on the properties of micro/nanocrystalline semiconductors.