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Electrolytes for Lithium and Lithium-ion Batteries provides a comprehensive overview of the scientific understanding and technological development of electrolyte materials in the last 10 years. This book covers not only the key electrolytes such as LiPF6 salt in mixed-carbonate solvents with additives for the state-of-the-art Li-ion batteries but also the new electrolyte materials developed recently that potentially lay the foundation for future advances. Characterization of electrolyte materials for their transport properties, structures, phase relationships, stabilities, and impurities is reviewed. Advances in the understanding of the electrode-electrolyte interactions and interphasial chemistries that are key for the successful use of the electrolyte in practical devices is also discussed. The Quantum Mechanical and Molecular Dynamical calculations that has proved to be so powerful in understanding and predicating behavior and properties of materials is a valuable part of the book.